Structure and bonding in rhodium coordination compounds: a ¹⁰³Rh solid-state NMR and relativistic DFT study

Holmes, S. T., Schönzart, J., Philips, A. B., Kimball, J. J., Termos, S., Altenhof, A. R., Xu, Y., O'Keefe, C. A., Autschbach, J., and Schurko, R. W.

2024Journal ArticleChemical Science 15, pp. 2181–2196

DOI: 10.1039/d3sc06026h

Abstract

We present the rapid and robust acquisition of ¹⁰³Rh solid-state NMR spectra for a series of inorganic and organometallic compounds. Relativistic DFT calculations provide relationships between ¹⁰³Rh chemical shift tensors, structure, and bonding.