Chemical stimulation of geothermal reservoirs using reactive flow-through system

Principal Investigator
Prof. Martin O. Saar, ETH Zurich
Co-Principal Investigator
Dr. Xiangzhao Kong, ETH Zurich
Researchers
Jin Ma
Start date
1 March 2016
Funding
DESTRESS: Horizon 2020 (European Commission) call:H2020-LCE-2015-2
Supervisor
Prof. Martin O. Saar, ETH Zurich

Description

This study is part of the DESTRESS project which follows the ambition to reliably increase system efficiency of enhanced geothermal systems (EGS). EGS uses artificial improvements of the hydraulic performance of a reservoir to allow a widespread usage of the huge untapped geothermal potential. The concept of chemical stimulation treatment of geothermal reservoirs has been developed by DESTRESS to optimize the EGS approach in a sustainable way and adapt it to the specific geological environments of Europe.
This study focuses on fluid-rock reactions and their consequences on rock properties of multi-mineral sandstones under geothermal reservoir conditions. An image-based approach is first developed to estimate the accessible surface area of each mineral using a Monte-Carlo algorithm where BET measurements are set as benchmark values of surface area. Then reactive flow-through experiments on sandstones are performed to investigate the reactivity of the reacting phase (dolomite) in a CO-charged brine. The participation efficiency of the accessible surfaces is quantified to delineate the effective surface area (ESA) evolution during the experiments. The evolution of the efficiency and ESA are later confirmed independently using a 2D numerical dissolution model. Finally, this project investigates the effect of mineral dissolution on the effective stress law for the rock permeability. This project provides in-sights on the hydro-chemical-mechanical coupling processes in a multi-mineral system, with the applications on geological carbon sequestration and chemical stimulation of geothermal reservoir when CO is considered as the working fluid.
References
A.J. Luhmann and X.-Z. Kong and B.M. Tutolo and N. Garapati and B.C. Bagley and M.O. Saar and W.E. Seyfried Jr. Experimental dissolution of dolomite by CO-charged brine at 100oC and 150 bar: Evolution of porosity, permeability, and reactive surface area, Chemical Geology, 380 pp.145-160 (2014)




